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Transition Metal-Catalyzed Generation and Trapping of the o-QDMs: The Applications in the Diels-Alde
o-Quinodimethane(o-QDM),a transient short-lived and highly reactive species,has attracted great curiosity from chemists ......
A Gold(I)-catalyzed Rearrangement of Alkynylaziridine Indoles for the Synthesis of Spiro-tetrahydro-
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Gold-Catalyzed Tandem Cyclization/Cycloaddition Reaction of Enynones:Highly Regioselective Synthesis
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利用密度泛函理论(DFT)在B3LYP/6-31G(d,p)(Au使用SDD)理论水平上对金催化苯硫酚与炔烃的氢硫化反应详细机理进行了系统研究,溶剂化效应......